Disk Commands by John Sisson is a part of the Commodore Educational series of programs.  This particular program is about learning the commands for the 4040 Disk System using DOS 2.0 and BASIC 4.0 on a PET, 8032 or C64.

Fisher Price - My Grand Piano is a music education program for ages 3 - 8 for the Commodore 64 or 128 (in C64 mode).  From what I could gather, I believe a hardware keyboard overlay accompanied this, but isn't necessary to use the software.

This is a cute educational game for kids to help them with pattern recognition.  There are various pictures that are displayed for a short amount of time then re-displayed with something missing in the picture you have to identify.  

This astronomy program, designed for persons ages 12 and up, was released in 1984 and included a 138-page manual. It provided an interactive guided tour of the universe—in the past, present, and future. The universe model could show the location of more than 1,200 stars, 88 constellations, 8 planets, deep sky objects, and the (then) future appearance (1986) of Halley’s comet. The program had four basic modes: map, set, sky, and chart. Map was used to select the location on Earth; month, day, year, and time were determined in set; optional displays were chosen in sky; and chart was used to project the sky on a celestial sphere with coordinate lines for creating, viewing, and printing your own star charts.

Here's are some links to the manual (including cheat sheet and easter eggs) and the addendum.

Speed Reader by Green Valley Publishing for the Commodore 64 is a tool for helping you learn to read faster.